- Title
- Ultrasonic-assisted preparation of highly reactive Fe-Zn sorbents supported on activated-char for desulfurization of COG
- Creator
- Dou, Jinxiao; Yu, Jianglong; Tahmasebi, Arash; Yin, Fengkui; Gupta, Sushil; Li, Xianchun; Lucas, John; Na, Chuan; Wall, Terry
- Relation
- Fuel Processing Technology Vol. 135, Issue July 2015, p. 187-194
- Publisher Link
- http://dx.doi.org/10.1016/j.fuproc.2015.01.035
- Publisher
- Elsevier
- Resource Type
- journal article
- Date
- 2015
- Description
- The desulfurization properties of Fe-Zn sorbent prepared by impregnating Fe and Zn into lignite char via ultrasonic-assisted impregnation (UAI) were investigated in comparison with the mechanical stirring (MS) method. The sulfidation experiments were carried out using a fixed-bed quartz reactor under ambient pressure. The amounts of metals loaded into char were measured by inductively coupled plasma atomic emission spectrometry (ICP-AES). The crystalline phases and chemical structure of sorbents before and after sulfidation were characterized by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR), respectively. The morphology of sorbents was analyzed by using scanning electron microscope (SEM) with an energy dispersive X-ray (EDX) auxiliary. The experimental results showed that metal oxides as the active components were evenly dispersed on char as nanoparticles. The impregnation of active components was significantly improved by the ultrasonic-assisted impregnation method. When sorbents were prepared by ultrasonic-assisted impregnation, the metal oxide particles became smaller and more evenly dispersed on the char matrix which resulted in higher desulfurization efficiency and sulfur uptake capacity of the sorbents. The BET results showed that the physical properties of sorbents (surface area and pore volume) significantly improved when prepared by UAI method compared to MS method. The sulfidation temperature had a significant effect on desulfurization performance of char supported sorbents. The Fe:Zn molar ratio of 2:1, and impregnation time of 9 h were suggested as the optimal preparation conditions during ultrasonic-assisted impregnation.
- Subject
- coke oven gas; sulfidation; char supported Fe–Zn sorbent; ultrasonic-assisted impregnation; sulfur capacity
- Identifier
- http://hdl.handle.net/1959.13/1338278
- Identifier
- uon:28002
- Identifier
- ISSN:0378-3820
- Language
- eng
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